Mechanistic Study of a Synthetically Useful Monooxygenase Model Using the Hypersensitive Probe trans-2-Phenyl-1-vinylcyclopropane

DOI: 10.1021/jo00023a008

Source and publish data:

Journal of Organic Chemistry p. 6497 - 6500 (1991)

Update date:2022-08-05

Topics:

Authors:

Fu, Hong

Look, Gary C.

Zhang, Wei

Jacobsen, Eric N.

Wong, Chi-Huey

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Article abstract of DOI:10.1021/jo00023a008

The use of trans-2-phenyl-1-vinylcyclopropane as a hypersensitive probe to study the epoxidation mechanisms of monooxygenases and their models is described; the high yield epoxide formation indicates that the Mn(III) salen mediated epoxidation of unfuncti

Full text of DOI:10.1021/jo00023a008

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