Sequential Peripheral Cyclopropanation as a Synthetic Approach to Cyclosubstituted Triangulanes

DOI: 10.1021/jo00094a016

Source and publish data:

Journal of Organic Chemistry p. 4087 - 4089 (1994)

Update date:2022-07-29

Topics: Cyclopropanation Sequential Peripheral

Authors:

Zefirov, Nikolai S.

Kuznetsova, Tamara S.

Eremenko, Olga V.

Kokoreva, Olga V.

Zatonsky, George

Ugrak, Bogdan I.

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Article abstract of DOI:10.1021/jo00094a016

A general scheme for the synthesis of cyclosubstituted triangulanes has been developed, based on sequential bromocyclopropanation of the C=C bond and elimination, giving repeatedly the endomethylenecyclopropane framework with termination of the sequence of the cyclopropanation.

Full text of DOI:10.1021/jo00094a016

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