Sequential Peripheral Cyclopropanation as a Synthetic Approach to Cyclosubstituted Triangulanes

DOI: 10.1021/jo00094a016

Source and publish data:

Journal of Organic Chemistry p. 4087 - 4089 (1994)

Update date:2022-07-29

Topics: Cyclopropanation Sequential Peripheral

Authors:

Zefirov, Nikolai S.

Kuznetsova, Tamara S.

Eremenko, Olga V.

Kokoreva, Olga V.

Zatonsky, George

Ugrak, Bogdan I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00094a016

A general scheme for the synthesis of cyclosubstituted triangulanes has been developed, based on sequential bromocyclopropanation of the C=C bond and elimination, giving repeatedly the endomethylenecyclopropane framework with termination of the sequence of the cyclopropanation.

Full text of DOI:10.1021/jo00094a016

Products guided by the article

Product name:bicyclo<6.1.0>non-1(2)-ene

Cas No:96308-41-7

R&D Labs maybe for 96308-41-7

HANGZHOU GOPHER CHEM-TECH CO.,LTD

Contact:86-189-58111780

Address:Da Cheng Ming Zuo Plaza,Xiaoshan District
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED

Contact:+86-0532-82683616

Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Changzhou Ansciep Chemical Co.,Ltd.

Contact:+86 519 8630 5871

Address:A-710 Boan International, 8 East Guangdian Road,Wujin,Changzhou
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China

Relevant to this article

Synthesis of Mitomycin C Analogues. 1. Introduction of the Urethane Function at C-10 of the Pyrrolo<1,2-a>indole Skeleton

Doi:10.1021/jo00220a023
(1985)
A new, efficient, two step procedure for the preparation of the antineoplastic agent sparfosic acid

Doi:10.1080/00397919708003363
(1997)
Flash Vacuum Pyrolysis of Organomanganese Pentacarbonyl Compounds

Doi:10.1021/ja00304a043
(1985)
Synthesis of new (trifluoromethyl)-1H-benzo[e][1,2,4]triazolo[1,2-a][1,2,4]triazine-1,3(2H)-diones and (trifluoromethyl)benzo[5,6][1,2,4]triazino [1,2-b]phthalazine-8,13-diones

Doi:10.1016/j.jfluchem.2016.12.004
(2017)
Reactions of 1-cyanoimidazoles with phenols

Doi:10.1023/A:1012401028728
(2001)
Aromatic Nucleophilic Substitution. 21. Electronic Structures of 1,3-Dinitro-4-phenanthryl Methyl Ether and the 4,4-Disubstituted 1,3-Dinitrophenanthrene Meisenheimer Complex

Doi:10.1021/jo00225a024
(1985)

Article Doi