Journal of Organic Chemistry p. 4087 - 4089 (1994)
Update date:2022-07-29
Topics: Cyclopropanation Sequential Peripheral
Zefirov, Nikolai S.
Kuznetsova, Tamara S.
Eremenko, Olga V.
Kokoreva, Olga V.
Zatonsky, George
Ugrak, Bogdan I.
A general scheme for the synthesis of cyclosubstituted triangulanes has been developed, based on sequential bromocyclopropanation of the C=C bond and elimination, giving repeatedly the endomethylenecyclopropane framework with termination of the sequence of the cyclopropanation.
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