Journal of the American Chemical Society p. 3625 - 3632 (1987)
Update date:2022-08-05
Topics:
Traylor, Teddy G.
Nakano, Taku
Miksztal, Andrew R.
Dunlap, Beth E.
During the course of hemin-catalyzed epoxidation of norbornene and other alkenes, the hemin catalyst is converted to N-alkylhemin by addition to the alkene.This transient species is a catalyst for epoxidation but is not an intermediate.As the oxidant disappears, the N-alkylhemin reverts to the original hemin.Proposed mechanisms that require the accumulation of other transients can be excluded because the N-alkylhemin is the only species that accumulates.
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