ON THE GENERATION OF STABILIZED LOW-VALENT METALLOCENE DERIVATIVES. THE DIRECT SYNTHESIS AND REDUCTIVE COUPLING REACTIONS OF 1-METHYLTHIOALKYNE-ZIRCONOCENE COMPLEXES

DOI: 10.1016/S0040-4039(00)99422-X

Source and publish data:

Tetrahedron Letters p. 3495 - 3498 (1989)

Update date:2022-08-02

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Authors:

Wagenen, Bradford C. Van

Livinghouse, Tom

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Article abstract of DOI:10.1016/S0040-4039(00)99422-X

4-Dimethylaminopyridine has been found to be a remarkably effective ligand for the formation of stabilized zirconocene complexes.The latter species mediate efficient coupling reactions between 1-methylthioalkynes and a variety of unsaturated organic substrates.

Full text of DOI:10.1016/S0040-4039(00)99422-X

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