EIN SIEBENGLIEDRIGER GERMANIUM-SILICIUM-SAUERSTOFF-RING: 1,1,2,2,4,4,6,6-OCTAPHENYL-1,2-DIGERMA-4,6-DISILA-3,5,7-TRIOXA-CYCLOHEPTAN

DOI: 10.1016/0022-328X(85)87103-5

Source and publish data:

Journal of Organometallic Chemistry p. 141 - 148 (1985)

Update date:2022-07-30

Topics:

Authors:

Puff, Heinrich

Koek, Tevfik Riza

Nauroth, Peter

Schuh, Willi

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Article abstract of DOI:10.1016/0022-328X(85)87103-5

Octaphenyl-digerma-disila-trioxane (Ph8Ge2Si2O3) has been synthesized by the reaction of ClPh2Ge-GePh2Cl with Ph2Si(OH)2.X-Ray analysis showed the presence of a new seven-membered germanium-silicon-oxygen ring with a germanium-germanium bond.The ring is only slightly puckered and has C₂ symmetry (twisted chair conformation).

Full text of DOI:10.1016/0022-328X(85)87103-5

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