An Efficient and Convenient Method for the Asymmetric Allylation of Aldehydes with Allyltrimethylsilane Catalyzed by Diphenylboryl Triflate

DOI: 10.1246/cl.1987.1121

Source and publish data:

Chemistry Letters p. 1121 - 1124 (1987)

Update date:2022-09-26

Topics:

Authors:

Mukaiyama, Teruaki

Ohshima, Masahiro

Miyoshi, Norikazu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.1121

In the presence of a catalytic amount of diphenylboryl triflate, aldehydes smoothly react with (S)-1-phenyl-1-trimethylsilyloxyethane and allyltrimethylsilane to afford the chiral homoallyl ethers in good yields with high stereoselectivities.

Full text of DOI:10.1246/cl.1987.1121

Products guided by the article

Product name:[(S)-1-((R)-1-Isopropyl-but-3-enyloxy)-ethyl]-benzene

Cas No:98088-53-0

R&D Labs maybe for 98088-53-0

Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Evershine Chemical CO Ltd

Contact:+86-571-87010026

Address:202, Zhenhua Road,
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.

Relevant to this article

Copper-Catalyzed Disulfonation of Terminal Alkynes with Sodium Arylsulfinates

Doi:10.1021/acs.orglett.0c00575
(2020)
Through-bond energy transfer cassettes with minimal spectral overlap between the donor emission and acceptor absorption: Coumarin-rhodamine dyads with large pseudo-stokes shifts and emission shifts

Doi:10.1002/anie.200904515
(2010)
Phthalocyanines prepared from 4-chloro-/4-hexylthio-5-(4-phenyloxyacetic acid)phthalonitriles and functionalization of the related phthalocyanines with hydroxymethylferrocene

Doi:10.1016/j.jorganchem.2009.09.025
(2010)
SYNTHESIS OF ENAMINOTHIOCARBONYL COMPOUNDS (IMIDAZOLIDINE NITROXYL RADICALS) AND THEIR REACTIONS WITH SODIUM HYPOBROMITE

Doi:10.1007/BF00959890
(1988)
Synthesis of the donor-acceptor ligand 2-(4-dimethylaminobenzylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (dbpcd) and X-ray diffraction structure of the platinum(II) compound PtCl₂(dbpcd)·1.5CH₂Cl₂

Doi:10.1016/j.ica.2009.11.011
(2010)
Facile Formation of Substituted 2-Butene-1,4-diylmagnesium Using Highly Reactive Magnesium: A Simple Approach to Complex Carbocycles and Functionalized Ketones

Doi:10.1021/jo00275a001
(1989)

Article Doi