An Efficient and Convenient Method for the Asymmetric Allylation of Aldehydes with Allyltrimethylsilane Catalyzed by Diphenylboryl Triflate

DOI: 10.1246/cl.1987.1121

Source and publish data:

Chemistry Letters p. 1121 - 1124 (1987)

Update date:2022-09-26

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Authors:

Mukaiyama, Teruaki

Ohshima, Masahiro

Miyoshi, Norikazu

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Article abstract of DOI:10.1246/cl.1987.1121

In the presence of a catalytic amount of diphenylboryl triflate, aldehydes smoothly react with (S)-1-phenyl-1-trimethylsilyloxyethane and allyltrimethylsilane to afford the chiral homoallyl ethers in good yields with high stereoselectivities.

Full text of DOI:10.1246/cl.1987.1121

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