Journal of Organic Chemistry p. 4114 - 4119 (1985)
Update date:2022-08-03
Topics:
Wenkert, David
Ferguson, Stephen B.
Porter, Barry
Qvarnstrom, Anders
McPhail, Andrew T.
3-Phenyl- and 3-unsubstituted-2-alkenoyl-1-methylaziridines have been synthesized via Grignard reactions with the corresponding 2-cyanoaziridines.The 3-phenylated-2-alkenoylaziridines have been thermally transformed into ring-fused pyrrolidine compounds.The configurations and conformations of the aziridine and pyrrolidine compounds have been determined by 1H and 13C NMR spectroscopy and X-ray crystallography.
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