ON THE CHEMISTRY OF LITHIUM DIALLYL CUPRATE

DOI: 10.1016/S0040-4039(00)84277-X

Source and publish data:

Tetrahedron Letters p. 1429 - 1432 (1986)

Update date:2022-07-29

Topics:

Authors:

Hutchinson, D. K.

Fuchs, P. L.

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Article abstract of DOI:10.1016/S0040-4039(00)84277-X

The anomalous addition reactions of lithium diallyl cuprate with enones and an amino vinyl sulfone are shown to not result from allyl lithium in equilibrium with allyl cuprate.A mechanism involving an ³η, 18-electron cuprate is proposed.

Full text of DOI:10.1016/S0040-4039(00)84277-X

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