Stereoselective Nucleophilic Substitution of 6-Methoxy-1-methoxycarbonylpipecolate: Enantioselective Synthesis of (+)-Sedamine from L-Lysine

DOI: 10.1039/c39850000633

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 633 - 635 (1985)

Update date:2022-08-02

Topics:

Authors:

Irie, K.

Aoe, K. Aoe, K.

Tanaka, T.

Saito, S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000633

Amidoalkylation 6-methoxy-1-methoxycarbonylpipecolate (4) with several nucleophiles gave the 2,6-cis 6-substituted pipecolates, stereoselectively.

Full text of DOI:10.1039/c39850000633

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(2S,6R)-6-(2-Oxo-2-phenyl-ethyl)-piperidine-1,2-dicarboxylic acid dimethyl ester

Cas No:98711-96-7

R&D Labs maybe for 98711-96-7

Suzhou Kangrun Pharmaceutical, Inc

Contact:86-512-63912376，63913329

Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Hangzhou innopharma technology Co,.Ltd.(expird)

Contact:+86-13388601988

Address:Room845,lixin building, moganshan road, hangzhou, china
Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China

Relevant to this article

Amides as precursors of imidoyl radicals in cyclisation reactions

Doi:10.1016/j.tet.2006.10.030
(2007)
Synthesis of an Optically Active Octahydro-2H-pyrido<1,2-a>pyrazine Based CNS Agent

Doi:10.1016/0957-4166(95)00003-8
(1995)
Studies toward the Syntheses of Functionally Substituted γ-Butyrolactones and Spiro-γ-butyrolactones and Their Reaction with Strong Acids: A Novel Route to α-Pyrones

Doi:10.1021/jo00271a023
(1989)
Catalytic Generation and Chemoselective Transfer of Nucleophilic Hydrides from Dihydrogen

Doi:10.1002/chem.201805530
(2019)
Stereocontrolled Total Synthesis of Lipoxins A

Doi:10.1021/ja00311a048
(1985)
Synthesis of 4-Methyl- and 4,4-Dimethyl-1,3-dioxin-2(4H)-one and Related Enol Carboxylates

Doi:10.1021/jo00225a069
(1985)

Article Doi