Carbohydrate Research p. 17 - 24 (1986)
Update date:2022-08-03
Topics:
Diksic, Mirko
Jolly, Dean
1,5-Anhydro-2-deoxy-D-arabino- (D-glucal), 1,5-anhydro-2-deoxy-D-lyxo- (D-galactal), and 3,4,6-tri-O-acetyl-1,5-anhydro-2-deoxy-D-lyxo-hex-1-enitol (3,4,6-tri-O-acetyl-D-galactal) (3) were fluorinated in water and organic solvent-water with molecular fluorine and, for 18F-labelled compounds, with <18F>fluorine.Chemical yields of 40 and 10percent were obtained for 2-deoxy-2-fluoro-D-glucose and 2-deoxy-2-fluoro-D-mannose, respectively, and 35 and 5percent for 2-deoxy-2-fluoro-D-galactose (12) and 2-deoxy-2-fluoro-D-talose (13), respectively.In the fluorination of 3, the chemical yields of 12 and 13 were 38 and 6percent, respectively.An l.c. separationof 2-deoxy-2-fluoro-D-hexoses is described.
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Doi:10.1016/j.bmcl.2013.10.071
(2013)Doi:10.1021/ja01542a023
(1958)Doi:10.1021/jm00151a018
(1986)Doi:10.1016/S0008-6215(00)90765-1
(1985)Doi:10.1021/ja01170a072
(1949)Doi:10.1021/jo00351a028
(1986)
