Journal of Organic Chemistry p. 1364 - 1367 (1988)
Update date:2022-07-31
Topics:
Shono, Tatsuya
Kise, Naoki
Tanabe, Takayoshi
The addition of electrogenerated dichloro(methoxycarbonyl)methyl anions to some N-(methoxycarbonyl)-α-amino aldehydes prepared from α-amino acids was found to show about 100percent diastereoselectivity.Some alkaloid type compounds containing pyrrolizidine and indolizidine skeletons were synthesized from the adducts.
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