Novel 2-Aza-allylidene Complexes: Synthesis and X-Ray Structure of trans-Br(CO)4W

DOI: 10.1039/c39850000537

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 537 - 539 (1985)

Update date:2022-08-05

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Authors:

Fischer, Helmut

Seitz, Friedrich

Riede, Juergen

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Article abstract of DOI:10.1039/c39850000537

The replacement of the trans-CO group by Br(1-) in cationic <(CO)5W=C=N=CR2>AlBr4 complexes causes a drastic change in the geometry of the CNCR2 ligand; the molecular structure of the phenyl-substituted product, trans-Br(CO)4W, is established by single crystal X-ray diffraction.

Full text of DOI:10.1039/c39850000537

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