
Chemistry Letters p. 643 - 646 (1985)
Update date:2022-08-03
Topics:
Nakadaira, Yasuhiro
Sato, Ryuji
Sakurai, Hideki
The reaction of diphenylacetylene with thermally generated cis- and trans-1,2-dimethyl-1,2-diphenyldisilene at 300 deg C gave a mixture of the <2+2> cycloadducts in a stereoselective but not completely stereospecific manner.A stepwise radical mechanism is suggested.
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