Tetrahedron Letters p. 2509 - 2512 (1993)
Update date:2022-08-03
Topics:
Okamoto, Sentaro
Tani, Kousuke
Sato, Fumie
Sharpless, K. Barry
Zargarian, Davit
Optically active, secondary allylic alcohols can be prepared from allylic silanes by the successive asymmetric dihydroxylation and Peterson olefination reactions.The effects of trialkylsilyl groups on the outcome of the AD reaction on vinyl and allyl silanes are also discussed.
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