A CONVERGENT ORGANOIRON APPROACH TO STEROID SYNTHESIS

DOI: 10.1016/S0040-4039(00)98597-6

Source and publish data:

Tetrahedron Letters p. 2981 - 2984 (1985)

Update date:2022-08-03

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Authors:

Pearson, Anthony J.

Ray, Tapan

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Article abstract of DOI:10.1016/S0040-4039(00)98597-6

The reaction of tricarbonyl (4-methoxy-1-methylcyclohexadienyl)iron hexafluorophosphate (1) with the keto ester nucleophile 5 to give complexes 6 and 7, and conversion of 6 in eight steps, via the enone 8a, to a D-homosteroid 11 is described.

Full text of DOI:10.1016/S0040-4039(00)98597-6

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