Derivatives of U(BH4)4 and its Lewis base adducts; synthesis of monocyclopentadienyl- and hydride-uranium(IV) complexes: (η-C5H5)U(BH4)3 and (CH3OCH2CH2OCH3)U(BH4)3H

DOI: 10.1016/0022-328X(88)80443-1

Source and publish data:

Journal of Organometallic Chemistry p. 123 - 130 (1988)

Update date:2022-07-29

Topics:

Authors:

Baudry, Denise

Ephritikhine, Michel

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Article abstract of DOI:10.1016/0022-328X(88)80443-1

In solution, (THF)2U(BH4)4 and (HMPA)2U(BH4)4 adopt a trans-configuration, whereas (Ph3PO)2U(BH4)4 exists as an equilibrium mixture of two isomers.Thermolysis of (DME)U(BH4)4 gives the corresponding uranium (IV) hydride (DME)U(BH4)3H.Raction of U(BH4)4 with TlCp or cyclopentadiene in toluene gives CpU(BH4)3.

Full text of DOI:10.1016/0022-328X(88)80443-1

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