Hydration of Diacetylene Compounds. Synthesis of a Marine Natural Product: (+/-)-1-(2,6,6-Trimethyl-4-hydroxycyclohexenyl)-1,3-butanedione

DOI: 10.1021/jo00353a022

Source and publish data:

Journal of Organic Chemistry p. 387 - 390 (1986)

Update date:2022-08-02

Topics:

Authors:

Constantino, Mauricio G.

Donate, Paulo M.

Petragnani, Nicola

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00353a022

The marine natural product (+/-)-1-(2,6,6-trimethyl-4-hydroxycyclohexenyl)-1,3-butanedione (1) was synthesized from known the keto alcohol 3 and 1,4-dichlorobut-2-yne.The synthetic sequence involves dehydration of the diyne tertiary alcohol 2 and hydratio

Full text of DOI:10.1021/jo00353a022

Products guided by the article

Product name:1-(2,6,6-trimethyl-1,4-dihydroxycyclohexyl)-1-butyn-3-one

Cas No:99810-22-7

R&D Labs maybe for 99810-22-7

Puyang Willing Chemicals Co.,Ltd.

Contact:86-393-4840366

Address:Puyang Henan China
Linyi VIHO Chemical Co.,Ltd

Contact:86-15588110016

Address:LINYI CITY,SHANDONG PROVINCE,CHINA
Zhuhai Rundu Pharmaceutical co.,Ltd

Contact:+86-756-7630755

Address:No.6,North Airport Road,Sanzao Town,Jinwan District
Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo
GUANGZHOU MEDCAN PHARMATECH LTD

website:http://www.gzmedcan.com

Contact:+86-20-82519649

Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China

Relevant to this article

A novel amphiphilic Re¹ complex with bis(fullerene)-substituted bipyridine ligands: Synthesis, electrochemistry, and langmuir film

Doi:10.1002/ejic.200600875
(2007)
Synthesis, spectroscopic characterization, electrochemical behaviour, reactivity and antibacterial activity of some transition metal complexes with 2-(N-salicylideneamino)-3-carboxyethyl-4,5-dimethylthiophene

Doi:10.1016/j.saa.2007.11.003
(2008)
Synthesis and biological activities of 5-thio-α-GALCERS

Doi:10.1021/acsmedchemlett.5b00046
(2015)
Desulfurization of the Epidithiopiperazinedione Sirodesmin PL with Triphenylphosphine: Retention of Configuration at the Bridgehead Carbon Atoms

Doi:10.1021/ja00354a036
(1983)
Four-membered heterocycles-containing 4-anilino-quinazoline derivatives as epidermal growth factor receptor (EGFR) kinase inhibitors

Doi:10.1016/j.bmcl.2013.07.049
(2013)
A Second Generation Synthesis of Benzyl Piperidine Derivatives: A Key Intermediate for the Preparation of SERT/5-HT_1A Dual Inhibitor

Doi:10.1021/acs.oprd.5b00207
(2015)

Article Doi