Hydration of Diacetylene Compounds. Synthesis of a Marine Natural Product: (+/-)-1-(2,6,6-Trimethyl-4-hydroxycyclohexenyl)-1,3-butanedione

DOI: 10.1021/jo00353a022

Source and publish data:

Journal of Organic Chemistry p. 387 - 390 (1986)

Update date:2022-08-02

Topics:

Authors:

Constantino, Mauricio G.

Donate, Paulo M.

Petragnani, Nicola

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Article abstract of DOI:10.1021/jo00353a022

The marine natural product (+/-)-1-(2,6,6-trimethyl-4-hydroxycyclohexenyl)-1,3-butanedione (1) was synthesized from known the keto alcohol 3 and 1,4-dichlorobut-2-yne.The synthetic sequence involves dehydration of the diyne tertiary alcohol 2 and hydratio

Full text of DOI:10.1021/jo00353a022

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