Inorganic Chemistry
Article
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CONCLUSION
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4
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3, 5468−5512.
In summary, we report a novel 3D Co(II)-MOF (1) which can
reversible bind MeOH at the Co(II) atom without loss of its
single crystallinity. The desolvated Co(II)-MOF (2) with open
Co(II) sites is very robust and can be stable up to 350 °C.
More importantly, it is a highly active recyclable solid catalyst
for oxidation of various organic substrates. The results indicate
that the open metal sites play a central role for the MOF-
catalytic oxidation.
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ASSOCIATED CONTENT
Supporting Information
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Additional characterization for 1, 1′, and 2, experimental
details for organic oxidation and GC-MS analysis, and
bond angles for 1, 1′, and 2 (PDF)
X-ray crystallographic data for CCDC 1405798 (CIF)
X-ray crystallographic data for CCDC 1405799 (CIF)
X-ray crystallographic data for CCDC 1405800 (CIF)
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AUTHOR INFORMATION
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(
Hupp, J. T. J. Am. Chem. Soc. 2011, 133, 5652−5655.
(17) Maksimchuk, N. V.; Kovalenko, K. A.; Fedin, V. P.; Kholdeeva,
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Notes
The authors declare no competing financial interest.
(
18) Long, J. L.; Wang, L. M.; Gao, X. F.; Bai, C. H.; Jiang, H. F.; Li,
Y. W. Chem. Commun. 2012, 48, 12109−12111.
ACKNOWLEDGMENTS
We are grateful for financial support from NSFC (Grant Nos.
1475078, 21271120, and 21201112), 973 Program (Grant
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