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Studies on Transition-metal Oxo and Nitrido Complexes. Part 9. Periodato and Tellurato Oxo-ruthenium Complexes as Organic Oxidants. X-Ray Crystal Structure of trans-NaK5*8H2O

DOI: 10.1039/DT9880001983

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1983 - 1988 (1988)

Update date:2022-08-29

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Authors:

El-Hendawy, Ahmed M.El-Hendawy, Ahmed M.

Griffith, William P.Griffith, William P.

Piggott, BrianPiggott, Brian

Williams, David J.Williams, David J.

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Article abstract of DOI:10.1039/DT9880001983

Salts of the anion trans-6-, earlier formulated as 6-, and of 6- have been prepared, and the X-ray crystal structure of the complex trans-NaK5*8H2O determined .Vibrational and electronic spectra for these diamagnetic 'ruthenyl' complexes are also reported.The periodato complexes function as overall six-electron oxidants in aqueous solution, converting primary alcohols to carboxylic acids and secondary alcohols to ketones; such reactions can be rendered catalytic if periodate is used as a co-oxidant.The tellurato complex functions as a two-electron oxidant for alcohols.

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