Tetrahedron Letters p. 9561 - 9564 (1995)
Update date:2022-08-10
Topics:
Meth-Cohn, Otto
Wang, Mei-Xiang
A powerful new nitrile hydratase organism, Rhodococcus rhodocrous AJ270 has been isolated that efficiently hydrolyses all kinds of nitriles to amides and/or acids.This paper shows that aromatic and heterocyclic nitriles are readily hydrolysed to acids but, that those bearing an adjacent-substituent (which may be an ortho substituent or an adjacent heteroatom in the ring) give amides in good yield but only slowly proceed to acids.
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