ChemCatChem p. 505 - 509 (2018)
Update date:2022-08-11
Topics:
Motoyama, Yukihiro
Morii, Koshi
Ishizuka, Shoya
Inomoto, Sou
Zhang, Zhenzhong
Yoon, Seong-Ho
Palladium nanoparticles supported on 5 %-nitrogen-doped, herringbone-type carbon nanofibers (Pd/N-CNF-H), which are prepared by thermally decomposing [Pd2(dba)3?CHCl3] (dba=dibenzylideneacetone) in toluene in the presence of N-CNF-H, were found to be an efficient catalyst for the chemoselective hydrogenation of alkenyl and nitro moieties in benzyl-protected alcohols and carboxylic acid derivatives with high turnover frequencies: the hydrogenation reactions of these functional groups proceeded smoothly even at ambient temperature under atmospheric H2 pressure, and the benzyl protecting groups in the molecules remained intact. Moreover, the recovered Pd/N-CNF-H catalyst could be reused without loss of its catalytic activity or chemoselectivity. The Pd/N-CNF-H catalyst also acted as an effective hydrogenation catalyst for the reduction of aromatic ketones to the corresponding benzyl alcohol derivatives with good to high product selectivity.
View MoreContact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
Beijing Cooperate Pharmaceutical Co.,Ltd
Contact:86-01060279497
Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Zibo Ocean International Trade Co.,Ltd(expird)
Contact:+86 533 5160706
Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
MTT Pharma & Bio-technology Co.,Ltd(expird)
Contact:+86-21-58407925
Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
Doi:10.1055/s-2004-822360
(2004)Doi:10.1039/CT9242500864
(1924)Doi:10.1021/ol000090c
(2000)Doi:10.1021/acscatal.5b00183
(2015)Doi:10.1016/S0040-4039(00)94245-X
(1986)Doi:10.1007/BF01558983
(1908)