Evidence for Proton Tunneling in the Strong Base Catalyzed Elimination Reaction of β-Phenylethyl Substrates

DOI: 10.1021/jo00206a018

Source and publish data:

Journal of Organic Chemistry p. 817 - 820 (1985)

Update date:2022-08-16

Topics:

Authors:

Kwart, Harold

Wilk, Kazimiera A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00206a018

The TDKIE criteria have been applied to some E2 (one-step) elimination reactions.The occurrence of proton tunneling in the course of the ethoxide ion promoted eliminations of β-phenylethyl substrates in ethyl alcohol is recognized by a temperature-depende

Full text of DOI:10.1021/jo00206a018

Products guided by the article

Product name:Phenylethene

Cas No:100-42-5

R&D Labs maybe for 100-42-5

Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

Relevant to this article

Structure elucidation and antimalarial activity of apicidin F: An apicidin-like compound produced by Fusarium fujikuroi

Doi:10.1021/np4006053
(2013)
The Transition-Metal Nitro-Nitrosyl Redox Couple: Catalytic Oxidation of Olefins to Ketones

Doi:10.1021/ja00400a081
(1981)
Natural organic acids promoted Beckmann rearrangement: Green and expeditious synthesis of amides under solvent-free conditions

Doi:10.2478/s11696-013-0481-y
(2014)
Copper/oxalohydrazide/ketone catalyzed synthesis of primary arylamines via coupling of aryl halides with aqueous ammonia in water

Doi:10.1016/j.tet.2011.05.068
(2011)
Transformative Evolution of Organolead Triiodide Perovskite Thin Films from Strong Room-Temperature Solid-Gas Interaction between HPbI₃-CH₃NH₂ Precursor Pair

Doi:10.1021/jacs.5b11824
(2016)
Enantioselectivity of Cocaine Recognition Sites: Binding of (1S)- and (1R)-2β-Carbomethoxy-3β-(4-iodophenyl)tropane (β-CIT) to Monoamine Transporters

Doi:10.1021/jm00065a014
(1993)

Article Doi