Hydrogenation with Ruthenium Catalysts
FULL PAPER
room temperature and the pressure was released. The resulting solution
was analyzed by GC analysis.
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[
[
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X-ray crystallographic study of [2]
A
H
R
U
G
4
]:
C
44
H
54BF
4
PRu
2
,
M=
À1
9
02.79 gmol , orthorhombic, Pna2
1
(no. 33), a=19.455(4), b=10.823(2),
3
c=18.805(4) , V=3959.6(14) , T=203K,
Z=4,
m(MoKa)=
A
H
R
U
G
À1
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0
.853mm
, 12579 reflections measured, 5769 unique (Rint =0.0441),
2
which were used in all calculations. The final wR (F ) value was 0.0504
all data). The data were measured with a Stoe Image Plate Diffraction
(
[
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2
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2
[
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9
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1
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2
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[
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[
[
[
CCDC-295104 contains the supplementary crystallographic data for this
paper. These data can be obtained free of charge from the Cambridge
Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
Acknowledgements
[
We thank Professor H. Stoeckli-Evans for free access to X-ray facilities
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Received: April 25, 2006
Published online: September 12, 2006
Chem. Eur. J. 2007, 13, 292 – 299
ꢁ 2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
299