Nucleophilic Displacement Catalyzed by Transition Metal. IX. *CHCl3-DPPF Catalyzed Cyanation of Aryl Halides and Aryl Triflates

DOI: 10.1246/bcsj.64.1118

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1118 - 1121 (1991)

Update date:2022-08-31

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Authors:

Takagi, Kentaro

Sasaki, Ken

Sakakibara, Yasumasa

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Article abstract of DOI:10.1246/bcsj.64.1118

A catalyst system comprising *CHCl3 and DPPF was proved to be efficient for the cyanation of aryl iodides and aryl triflates with KCN.The reactivities of aryl substrates decreased in the order ArI > ArOTf > ArBr.

Full text of DOI:10.1246/bcsj.64.1118

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