Electrosynthesis of (trifluoromethyl)copper complexes from bromotrifluoromethane: reactivities with various organic halides

DOI: 10.1016/0022-328X(94)05154-4

Source and publish data:

Journal of Organometallic Chemistry p. 137 - 144 (1995)

Update date:2022-08-12

Topics:

Authors:

Paratian, J. M.

Labbe, E.

Sibille, S.

Perichon, J.

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Article abstract of DOI:10.1016/0022-328X(94)05154-4

The synthesis of (trifluoromethyl)copper complexes is achieved easily by electroreduction of bromotrifluoromethane in N,N-dimethylformamide, in the presence of a sacrificial copper anode and various potential ligands.Three (trifluoromethyl)copper species are considered; two copper(II) and one copper(I).The mechanism of formation of the (trifluoromethyl)copper species is discussed and a study of their reactivities towards various organic halides is reported. Keywords: Copper; Trifluoromethyl derivatives; Electroreduction; Mechanism; Bromotrifluoromethane; (Trifluoromethyl)copper complexes

Full text of DOI:10.1016/0022-328X(94)05154-4

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