Journal of Organometallic Chemistry p. 137 - 144 (1995)
Update date:2022-08-12
Topics:
Paratian, J. M.
Labbe, E.
Sibille, S.
Perichon, J.
The synthesis of (trifluoromethyl)copper complexes is achieved easily by electroreduction of bromotrifluoromethane in N,N-dimethylformamide, in the presence of a sacrificial copper anode and various potential ligands.Three (trifluoromethyl)copper species are considered; two copper(II) and one copper(I).The mechanism of formation of the (trifluoromethyl)copper species is discussed and a study of their reactivities towards various organic halides is reported. Keywords: Copper; Trifluoromethyl derivatives; Electroreduction; Mechanism; Bromotrifluoromethane; (Trifluoromethyl)copper complexes
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