Tetrahedron p. 9187 - 9194 (1998)
Update date:2022-08-15
Topics:
Corsaro, Antonino
Librando, Vito
Chiacchio, Ugo
Pistara, Venerando
Rescifina, Antonio
Mesitonitrile oxide, but not benzonitrile oxide, adds to aza-analogues of phenanthrene to give low yields of monocycloadducts. Only phenanthridine reacts with the two nitrile oxides affording phenanthridinone. 4,7- phenanthroline also gives some other minor products among which the bisadduct to a pyridine ring was isolated. The reactivity of aza-analogues under examination is discussed in terms of FMO approximation.
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