The use of - for the carbonylation of primary, secondary and allylic halides

DOI: 10.1016/0022-328X(90)85244-S

Source and publish data:

Journal of Organometallic Chemistry p. 195 - 201 (1990)

Update date:2022-08-12

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Authors:

Davies, Stephen G.

Smallridge, Andrew J.

Ibbotson, Arthur

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Article abstract of DOI:10.1016/0022-328X(90)85244-S

The tricarbonyl nitrosyl ferrate anion (1) is an efficient carbonylation reagent for the formation of methyl esters from primary and secondary alkyl and benzyl halides.The carbonylation of allyl halides results in the exclusive formation of β,γ-unsaturated esters.Studies of the catalytic use of 1 are also described.

Full text of DOI:10.1016/0022-328X(90)85244-S

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