RUTHENIUM COMPLEX CATALYZED INTERMOLECULAR HYDROACYLATION OF OLEFINES

DOI: 10.1016/S0040-4039(00)61854-3

Source and publish data:

Tetrahedron Letters p. 6229 - 6230 (1987)

Update date:2022-08-11

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Authors:

Kondo, Teruyuki

Tsui, Yasushi

Watanabe, Yoshihisa

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Article abstract of DOI:10.1016/S0040-4039(00)61854-3

Dodecacarbonyltriruthenium (Ru3(CO)12) and (η⁴-1,5-cyclooctadiene)(η⁶-1,3,5-cyclooctatriene)ruthenium (Ru(COD)(COT) catalyzed the hydroacylation of olefins with aldehydes at 180-200 deg C for 48 h under 20 kgcm^-2 of carbon monoxide to give unsymmetric ketones in good yields.

Full text of DOI:10.1016/S0040-4039(00)61854-3

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