Catalytic Formation of Biaryls from Arenes through C-H Bond Activation by RhCl(CO)(PMe3)2 under Irradiation

DOI: 10.1246/cl.1987.2211

Source and publish data:

Chemistry Letters p. 2211 - 2214 (1987)

Update date:2022-08-30

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Authors:

Sakakura, Toshiyasu

Sodeyama, Touru

Tokunaga, Yuko

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1987.2211

Arenes were dehydrogenatively coupled into biaryls catalyzed by RhCl(CO)(PMe3)2 at room temperature under irradiation.The regioselectivity obtained in the reaction of toluene suggested the presence of a radical intermediate.

Full text of DOI:10.1246/cl.1987.2211

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