Journal of the Chemical Society. Chemical communications p. 1039 - 1041 (1987)
Update date:2022-08-11
Topics:
Falicky, Slavomir
Alper, Howard
Benzyl bromides are converted into oxime ethers by bubbling nitric oxide through a solution of the bromide in t-pentyl alcohol-3 M aqueous sodium hydroxide containing a palladium or ruthenium complex as catalyst and a quaternary ammonium salt as phase transfer agent; this provides the first example of a catalytic reaction of halides which involves free or co-ordinated nitric oxide and is also the first report of a phase transfer reaction utilizing nitric oxide as a reactant.
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