Tetrahedron Letters p. 1859 - 1862 (1997)
Update date:2022-08-11
Topics:
Popov, Konstantin A.
Polozov, Alexander M.
Tcherezov, Sergei V.
Diazoacetates 1a,b undergo BF3 · OEt2 catalyzed carbenoid attack on the oxygen of the phosphoryl double bond of phosphate triesters 2a-c or on the sulfur of thiophosphoryl double band of thiophosphate 9 to form corresponding O-alkoxycarbonylmethylphosphates 3a-c or S-alkoxycarbonylmethylphosphate 13.
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