Tetrahedron Letters p. 4133 - 4136 (1989)
Update date:2022-08-11
Topics:
Yamamoto, Hiroshi
Mashino, Tadahiko
Nagano, Tetsuo
Hirobe, Masaaki
The reaction of CO2 with superoxide cooxidized sulfides and olefins to the corresponding sulfoxides and epoxides, respectively, in dimethylformamide.The peroxy intermediates, CO4.- and C2O6.-, generated in situ from superoxide and CO2, were proposed as the ultimate oxidants in the oxidations.
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