μ-BIS(CYANOTRIHYDROBORATO)-TETRAKIS(TRIPHENYLPHOSPHINE) DICOPPER(I). A NEW, SELECTIVE, pH DEPENDENT REDUCING AGENT

DOI: 10.1016/S0040-4039(00)71512-7

Source and publish data:

Tetrahedron Letters p. 813 - 816 (1980)

Update date:2022-08-30

Topics:

Authors:

Hutchins, Robert O.

Markowitz, Morris

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Article abstract of DOI:10.1016/S0040-4039(00)71512-7

The title compound selectively reduces acid chlorides to aldehydes under neutral conditions and aldehydes and ketones to alcohols in acidic media. 4-tert-Butylcyclohexanone is reduced to the trans alcohol with a high degree of stereoselectivity (94:6).

Full text of DOI:10.1016/S0040-4039(00)71512-7

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