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Carbene Reactions. Part 16. Thermolyses of Norbornadiene-7-spiro-2'-(1',3'-dithiolane) S-Oxides

DOI: 10.1039/P29830001687

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1687 - 1692 (1983)

Update date:2022-08-17

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Authors:

Hoffmann, Reinhard W.Hoffmann, Reinhard W.

Barth, WolfgangBarth, Wolfgang

Carlsen, LarsCarlsen, Lars

Egsgaard, HelgeEgsgaard, Helge

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Article abstract of DOI:10.1039/P29830001687

The gas-phase thermolysis of the norbornadienespirodithiolane S-oxides (5) and (7) led to benzene, ethylene, and carbon disulphide as the major products, possibly involving carbon disulphide oxides as intermediates.Thermolyses of the related sulphones (9) or (14) led to completely different product patterns.

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Product name:Benzaldehyde

Cas No:100-52-7

100-52-7

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