Chemistry Letters p. 1831 - 1834 (1984)
Update date:2022-08-30
Topics:
Kakimoto, Masa-aki
Imai, Yoshio
It was found that PPSE catalyzed Pummerer rearrangement of various types of sulfoxides.When α-(phenylsulfinyl)acetophenone was used as sulfoxide, unusual product, phenyl phenylthioglyoxylate was isolated.The reaction seems to proceed via phosphorylation of oxygen of sulfoxides.
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