Kinetics of Alkene Oxidation by Cationic trans-Dioxoruthenium(VI) Complexes. Effect of Driving Force on Rate Constants

DOI: 10.1039/DT9920003153

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3153 - 3158 (1992)

Update date:2022-08-15

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Authors:

Che, Chi-Ming

Li, Chi-Keung

Tang, Wai-Tong

Yu, Wing-Yiu

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Article abstract of DOI:10.1039/DT9920003153

The kinetics of alkene oxidation by a series of isostructural trans-dioxoruthenium(VI) complexes with E⁰(Ru^VI-Ru^V) ranging from 0.23 to 0.7 V vs. saturated calomel electrode has been investigated in acetonitrile.The experi

Full text of DOI:10.1039/DT9920003153

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