Aluminum chloride (AlCl3) promotes selective oxidative deprotection of benzylic trimethylsilyl and tert-butyldimethylsilyl ethers to the corresponding carbonyl compounds with manganese dioxide (MnO2)

Article abstract of DOI:10.1080/00397919908086594

Various types of trimethylsilyl and tert-butyldimethylsilyl ethers of primary and secondary benzylic alcohols could be selectively converted to their corresponding carbonyl compounds with MnO₂ in the presence of AlCl₃ in good to excellent yields.

Full text of DOI:10.1080/00397919908086594

Synthetic Communications
ISSN: 0039-7911 (Print) 1532-2432 (Online) Journal homepage: http://www.tandfonline.com/loi/lsyc20
Aluminum Chloride (Alcl3) Promotes Selective
Oxidative Deprotection of Benzylic Trimethylsilyl
and Tert- Butyldimethylsilyl Ethers to the
Corresponding Carbonyl Compounds with
Manganese Dioxide (Mno2)
Habib Firouzabadi , Shahrad Etemadi , Babak Karimi & Ali Asghar Jarrabpour
To cite this article: Habib Firouzabadi , Shahrad Etemadi , Babak Karimi & Ali Asghar
Jarrabpour (1999) Aluminum Chloride (Alcl3) Promotes Selective Oxidative Deprotection of
Benzylic Trimethylsilyl and Tert- Butyldimethylsilyl Ethers to the Corresponding Carbonyl
Compounds with Manganese Dioxide (Mno2), Synthetic Communications, 29:24, 4333-4339,
DOI: 10.1080/00397919908086594
To link to this article: http://dx.doi.org/10.1080/00397919908086594
Published online: 25 Sep 2007.
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Date: 11 February 2016, At: 07:48