Journal of Organic Chemistry p. 840 - 843 (1983)
Update date:2022-08-11
Topics:
Matsumoto, Hideyuki
Inaba, Shin-ichi
Rieke, Reuben D.
Activated metallic nickel powder, prepared by the reduction of nickel halides with lithium and with naphthalene as an electron carrier, is a simple and convenient reagent for the dehalogenative coupling of iodobenzenes and bromobenzenes under mild conditions.The intermediates, ArNiX and Ar2Ni species (Ar=C6F5), were isolated as the phosphine complexes.
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