Journal of Physical Chemistry p. 3437 - 3442 (1993)
Update date:2022-08-24
Topics:
Garcia-Rio, Luis
Leis, J. Ramon
Pena, M. Elena
Iglesias, Emilia
The kinetics of the transfer of the nitroso group from N-methyl-N-nitroso-p-toluenesulfonamide to each of seven secondary amines (piperazine, N-methylbenzylamine, piperidine, dimethylamine, morpholine, pyrrolidine, and diisopropylamine) was studied using a wide variety of water/AOT/isooctane microemulsions as reaction media.The diverse kinetic behavior of the various amines can be explained quantitatively on the basis of a single model taking into account the distribution of the amine among the aqueous and isooctane phases and their mutual interface; the reaction itself always takes place at the interface.The relative reactivities of the amines are discussed in comparison with the order observed in water.
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