Journal of the Chemical Society. Chemical communications p. 1625 - 1626 (1994)
Update date:2022-08-11
Topics:
Mahapatra, Samiran
Halfen, Jason A.
Tolman, William B.
In a reaction relevant to environmentally important processes carried out by copper-containing enzymes and heterogeneous catalysts, copper(I) complexes of 1,4,7-triisopropyl-1,4,7-triazacyclononane dissolved in alcohols (e.g. benzyl alcohol) efficiently promote the reduction of NO to N2O by the solvent at room temperature, yielding the respective carbonyl compounds (e.g. benzaldehyde).
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