Journal of Physical Chemistry p. 2491 - 2496 (1986)
Update date:2022-08-16
Topics:
Hammer, Philip D.
Dlugokencky, Edward J.
Howard, Carleton J.
The rate constant for the reaction NO + NO3 --> 2NO2 was measured over the temperature range of 209-414 K by using laser-induced fluorescence detection of NO3 in a flow tube reactor.Our recommended results are k(T) + (1.55 +/- 0.23) * 10-11 exp<(195 +/- 39)/T> cm3 molecule-1 s-1 for T -11 cm3 molecule-1 s-1 for T > 300 K.These two expressions were required to describe the observed non-Arrhenius behavior of k(T).
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