Regiospecific Carbonylation and Ring Expansion of Thietanes and Oxetanes Catalyzed by Cobalt and/or Ruthenium Carbonyls

DOI: 10.1021/jo00262a010

Source and publish data:

Journal of Organic Chemistry p. 20 - 21 (1989)

Update date:2022-08-29

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Authors:

Wang, Ming-De

Calet, Serge

Alper, Howard

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Article abstract of DOI:10.1021/jo00262a010

Dicobalt octacarbonyl and triruthenium dodecacarbonyl together catalyze the regiospecific insertion of carbon monoxide into the least substituted carbon-heteroatom bond of a thietane or oxetane, affording thiobutyrolactones or butyrolactones in fine yields.

Full text of DOI:10.1021/jo00262a010

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