Studies on Polyoxo- and Polyperoxo-metalates. Part 1. Tetrameric Heteropolyperoxotungstates and Heteropolyperoxomolybdates

DOI: 10.1039/DT9930002683

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2683 - 2688 (1993)

Update date:2022-08-17

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Authors:

Dengel, Andrew C.

Griffith, William P.

Parkin, Bernardeta C.

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Article abstract of DOI:10.1039/DT9930002683

New heteropolyperoxometalates of the type R34> (3+) (en = ethane-1,2-diamine); X = P or As; M = Mo or W> have been characterized by IR, Raman and where appropriate 31P NMR spectroscopy.Epoxidation of cyclic and linear alkenes by these species with H2O2 as co-oxidant has been studied; 4>(3-) was found to be the most effective.The oxidation of alcohols by 4>(3-) with H2O2 has been investigated.

Full text of DOI:10.1039/DT9930002683

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