Total synthesis of verticillene. A biomimetic approach to the taxane family of alkaloids

DOI: 10.1016/S0040-4020(01)85602-7

Source and publish data:

Tetrahedron p. 4907 - 4924 (1990)

Update date:2022-08-12

Topics:

Authors:

Begley, Michael J.

Jackson, Christopher B.

Pattenden, Gerald

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Article abstract of DOI:10.1016/S0040-4020(01)85602-7

Intramolecular reductive coupling of the bis-aldehyde (10) in the presence of Ti(O), followed by 1,4-reducdon of the resulting tetraene (9) using sodium in ammonia, provides a facile synthesis of E,E-verticillene (8), the putative biogenetic precursor of

Full text of DOI:10.1016/S0040-4020(01)85602-7

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