Nucleophilic properties of butyllithium versus free carboxylic acids

DOI: 10.1016/0040-4039(91)85082-G

Source and publish data:

Tetrahedron Letters p. 2771 - 2774 (1991)

Update date:2022-08-11

Topics:

Authors:

Einhorn Einhorn

Luche Luche

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)85082-G

In opposition to the generally accepted idea, butyl lithium is not only a deprotonating agent for free carboxylic acids, but can also act as a nucleophile on the carbon oxygen double bond.

Full text of DOI:10.1016/0040-4039(91)85082-G

Products guided by the article

Product name:Valerophenone

Cas No:1009-14-9

R&D Labs maybe for 1009-14-9

Chemieliva Pharmaceutical Co., Ltd.

website:http://www.chemieliva.com

Contact:+86-23-67770219

Address:99 Longhua Road, Yubei District, 401147, Chongqing, China Email: sales@chemieliva.com Tel:0086-23-67770219 Fax: 0086-23-67770220 Attn: Andy Huang
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Tianjin Derchemist Sci-Tech Co., Ltd.

website:http://www.derchemist.com

Contact:+86-22-58627059

Address:Xinmao Science and Technology Park，Huayuan Industrial Park
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Ningbo Huajia Chemicals

Contact:+86-574-87065746

Address:10th Floor, No.787 Baizhang East Road,

Relevant to this article

Transition-metal-promoted chemoselective photoreactions at the cucurbituril rim

Doi:10.1002/anie.201005317
(2011)
Ti₃C₂T_x (T = F, OH) MXene nanosheets: Conductive 2D catalysts for ambient electrohydrogenation of N₂ to NH₃

Doi:10.1039/c8ta09840a
(2018)
A Facile Reduction Procedure for N,N′-bis[5-Substituted Salicylidene]-m/p-phenylenediamines with Sodium Borohydride-Silica Gel System

Doi:10.1081/SCC-120028641
(2004)
Immobilization of ruthenium(II) salen complexes on poly(4-vinylpyridine) and their application in catalytic aldehyde olefination

Doi:10.1016/j.tetlet.2006.12.135
(2007)
Carbanionic rearrangements of halomethylenecyclobutanes. The role of the halogen

Doi:10.1021/jo9810866
(1998)
Nile Red-Based GPCR Ligands as Ultrasensitive Probes of the Local Lipid Microenvironment of the Receptor

Doi:10.1021/acschembio.0c00897
(2021)

Article Doi