Journal of Physical Chemistry p. 1423 - 1427 (1985)
Update date:2022-08-29
Topics:
Smith, C. A.
Ravishankara, A. R.
Wine, P. H.
A discharge flow-long path laser absorption apparatus has been utilized to measure absolute rate constants for the recombination reaction NO2 + NO3 + M -> N2O5 +M at 298 K over the pressure ranges of 0.5 - 6.0 torr of N2 and 1.0 - 8.0 torr of He.The title reaction is found to be in the falloff regime between third- and second-order kinetics over this pressure range.Falloff parameters were obtained by fitting the kinetic data to the falloff equation of Troe and co-workers.A fitted falloff expression of our data in conjunction with recently published rate coefficients for N2O5 decomposition was employed to calculate Keq(298) and ΔHf0(298) for NO3.
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