NO(B 2Πr and A 2Σ+) chemiluminescence from the reaction C+NO2CO+NO at 300 K

Article abstract of DOI:10.1063/1.448327

The C + NO2 <*> CO + NO reaction at 300 K has been shown to exhibit a strong ultraviolet chemiluminescence from NO (B <*>) and a weak one from NO(A <*>).The NO (B <*>)ν' = 0 production rate was found to be approximately ten times greater than that of NO (A <*>)<*>.No chemiluminescence either from NO(C <*>) or NO (D <*>), however energetically accessible, could be observed.These features are in close agreement with the Cs symmetry correction diagram for this reaction.The nascent vibrational distribution of NO(B <*>) was found to be much cooler than the prior statistical one.

Full text of DOI:10.1063/1.448327

NO(B 2Π r and A 2Σ+) chemiluminescence from the reaction C+NO2→CO+NO at 300
K
G. Dorthe, J. Caille, S. Burdenski, P. Caubet, M. Costes, and G. Nouchi
Citation: The Journal of Chemical Physics 82, 2313 (1985); doi: 10.1063/1.448327
View online: http://dx.doi.org/10.1063/1.448327
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/82/5?ver=pdfcov
Published by the AIP Publishing
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