Journal of the Chemical Society. Chemical communications p. 1056 - 1058 (1984)
Update date:2022-08-11
Topics:
Crombie, Leslie
Wyvill, Robert D.
The (Z)/(E) composition of olefinic alcohols produced by sodium ring-scission of cyclic β-halogeno-ethers can be accounted for by a mechanism involving fast electron transfer and carbanion inversion, with ring-cleavage speedier than conformational inversion.
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