Metal Ion Catalysis by Blocking Inhibitory Reverse Paths in the Hydrolysis of 3-Carboxyaspirin

DOI: 10.1021/ja00271a041

Source and publish data:

Journal of the American Chemical Society p. 3057 - 3063 (1986)

Update date:2022-08-31

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Authors:

Suh, Junghun

Chun, Keun Ho

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Article abstract of DOI:10.1021/ja00271a041

The hydrolysis of 3-carboxyaspirin (1) was kinetically investigated in the presence or absence of tri- or divalent metal ions.The spontaneous hydrolysis of the neutral and the monoanionic forms of 1 involves anhydride intermediates formed by the nucleophi

Full text of DOI:10.1021/ja00271a041

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