Synthesis of Novel Chiral Ruthenium Complexes of 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl and their Use sa Asymmetric Catalysts

DOI: 10.1039/c39850000922

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 922 - 924 (1985)

Update date:2022-08-16

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Authors:

Ikariya, Takao

Ishii, Youichi

Kawano, Hiroyuki

Arai, Tsuneta

Saburi, Masahiko

et al. et al.

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Article abstract of DOI:10.1039/c39850000922

Reactions of n (COD = cyclo-octa-1,5-diene) with the chiral bidentate phosphine ligands 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, BINAP, and 2,2'bis(di-p-tolylphosphino)-1,1'binaphthyl, p-tolyl-BINAP, give new chiral ruthenium(II) complexes, Ru2Cl4(BINAP)2(NEt3) and Ru2Cl4(p-tolyl-BINAP)2(NEt3) respectively, which serve as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides.

Full text of DOI:10.1039/c39850000922

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