Welcome to LookChem.com Sign In|Join Free

Article Doi

Synthesis of Novel Chiral Ruthenium Complexes of 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl and their Use sa Asymmetric Catalysts

DOI: 10.1039/c39850000922

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 922 - 924 (1985)

Update date:2022-08-16

Topics:

Authors:

Ikariya, TakaoIkariya, Takao

Ishii, YouichiIshii, Youichi

Kawano, HiroyukiKawano, Hiroyuki

Arai, TsunetaArai, Tsuneta

Saburi, MasahikoSaburi, Masahiko

et al.et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000922

Reactions of n (COD = cyclo-octa-1,5-diene) with the chiral bidentate phosphine ligands 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, BINAP, and 2,2'bis(di-p-tolylphosphino)-1,1'binaphthyl, p-tolyl-BINAP, give new chiral ruthenium(II) complexes, Ru2Cl4(BINAP)2(NEt3) and Ru2Cl4(p-tolyl-BINAP)2(NEt3) respectively, which serve as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides.

View More

Products guided by the article

Product name:N-ACETYL-D-PHENYLALANINE

Cas No:10172-89-1

10172-89-1

R&D Labs maybe for 10172-89-1

Relevant to this article

Hot Product